The other members of the road-race team are Andrea Bagioli, Filippo Baroncini, Alberto Bettiol, Daniel Oss, Andrea Pasqualon, Lorenzo Rota, Kristian Sbaragli and Simone Velasco.
Filippo Ganna, meanwhile, will seek to win the time-trial world title for the third time on Friday.
The 27-year-old, who is also a track cycling Olympic gold medallist and multiple world champion, won the event in 2020 and 2021.
“We are not starting out as favourites, but anything can happen in a one-day race,” said Bennati.
“Italy has a great tradition at the world championships. The goal is to win.”
ANSA