Mr Zonfrillo's shock death has been confirmed by broadcaster Network 10.
The program will not air this week.
Zonfrillo spoke to Il Globo in 2017, you can read the article here.
Network 10 released a statement expressing their shock and sadness.
“Network 10 and Endemol Shine Australia are deeply shocked and saddened at the sudden loss of Jock Zonfrillo, a beloved member of the MasterChef Australia family.
“Jock passed away in Melbourne yesterday,” the statement read.
“Jock was known to Australians as a chef, best-selling author, philanthropist and MasterChef judge but he will be best remembered as a loving father, husband, brother and son.
“Determined and talented and with plenty of grit, Jock was born in Glasgow to an Italian father and a Scottish mother, which meant his formative years were heavily influenced by two strong cultures and it was his obsession with food and desire for a new pushbike that at just 12 years old fuelled Jock to knock on kitchen doors looking for a job.
“Jock’s love and passion for food saw him become one of the youngest culinary students to do an apprenticeship at The Turnberry Hotel at just 15 years of age.
“From that point onwards there was no holding him back and by 17 he was working alongside Marco Pierre White at his eponymous Restaurant Marco Pierre White.
“Throughout his career he worked with world famous chefs and in restaurants all over the world.
“His talent saw him shine in the world’s most formidable kitchens and he opened Bistro Blackwood and Restaurant Orana in Adelaide after moving to Australia.
“Jock’s charisma, wicked sense of humour, generosity, passion and love for food and his family cannot be measured. He will be greatly missed.”
AAP